One-pot Crabbé homologation-radical cascade cyclisation with memory of chirality.
نویسندگان
چکیده
The tandem Crabbé homologation-radical rearrangement of terminal enediynes leads, in a one-pot procedure, to the enantioselective synthesis of six- and seven-membered ring α-aminoesters bearing a quaternary stereocenter based on the phenomenon of memory of chirality.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 19 شماره
صفحات -
تاریخ انتشار 2012